If you don't have a G-Series keyboard with an LCD screen, you can use Windows Task Manager to find the active .exe file for a game.
NOTE: Use this method only if you don't know the location of the correct .exe file to associate to a profile. You can also use a G-Series keyboard with an LCD screen to find the active .exe for a game. See answer 360023190434 for help.
To find the active .exe for a game using Task Manager:
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Open the Logitech Gaming Software:
Start > All Programs > Logitech > Logitech Gaming Software 8.x
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Click the glowing G-Keys.
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Right-click the profile you want to configure and select Properties.
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Click the "…" by the "Select Game Executable" option.
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With this window open, launch the game you want to associate it with and progress past the game menus to where you would begin playing.
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Press and hold the Alt key and press Tab to get back to Windows, leaving the game running in the background.
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Press Ctrl + Alt + Del and select "Start Task Manager.
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In Task Manager, right-click the game you want to associate your profile with and select "Go To Process.
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In the next window, right-click the highlighted .exe file and select "Open File Location."
A Windows Explorer window will appear that shows the .exe of the game.
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To find the directory of the game, click once in the file address bar at the top of the window. Windows will display the current directory.
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Return to your Logitech Gaming Software window you left opened, browse to that directory, select the game .exe and click OK.
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The path should now be visible in your LGS window. Click OK to save the profile association.
Your profile should now be associated correctly with your game.